This article has been reviewed according to Science X's editorial process and policies. Editors have highlighted the following attributes while ensuring the content's credibility: From targeted cancer treatments to self-healing materials and microscopic robots, many emerging technologies depend on molecules that can be controlled with light. Researchers at Tohoku University have now developed a way to make these light-responsive molecules much more sensitive to visible light by using a molecular antenna.
The breakthrough gives scientists better control over molecular photoswitches remotely and potentially expands their use in medicine and advanced materials. The findings are published in the Journal of the American Chemical Society. "One of the biggest challenges has been developing photoswitches that respond efficiently to visible light without compromising their thermal stability," says Ryojun Toyoda, an assistant professor at Tohoku University's Graduate School of Science.
"Our molecular antenna strategy overcomes this trade-off, allowing us to harvest visible light much more effectively while preserving the switching behavior that practical applications require." For many real-world applications, photoswitches must function deep inside materials or biological tissues, where light loses intensity as it is scattered. Visible light is especially attractive because it penetrates these environments more effectively than ultraviolet light. However, most conventional azobenzene photoswitches are relatively insensitive to visible wavelengths, and previous efforts to improve their performance often reduced their stability.
To solve this problem, the researchers collaborated with Professor Shirin Faraji's group at Heinrich Heine University Düsseldorf to design azobenzene molecules equipped with dipyrrin complexes that act as highly efficient molecular antennae. These antennae absorb visible light before transferring the captured energy directly to the azobenzene unit, triggering its structural transformation. The team developed two types of hybrid molecules.
One linked azobenzene to a simple boron-based dipyrrin complex, while the other incorporated one-dimensional dipyrrin-zinc nanochains that transport energy along the molecular backbone. Through repeated separation processes, the researchers successfully isolated zinc nanochains of 10 discrete lengths, enabling them to investigate how molecular size affects performance. Using UV-visible absorption spectroscopy and proton nuclear magnetic resonance (¹H NMR), the researchers confirmed that the dipyrrin antennae efficiently transferred absorbed light energy to the azobenzene photoswitch.
In the zinc nanochain structures, the chains acted as molecular energy highways, transporting excitation energy over long distances to the terminal azobenzene unit. The new design produced some of the highest visible-light sensitivities reported for azobenzene photoswitches. The boron-based hybrid achieved a sensitivity of 7,500 M⁻¹ cm⁻¹, while the longest zinc nanochain reached 8,100 M⁻¹ cm⁻¹.
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