MOF-coated catalyst converts CO₂ to CO nearly five times faster under ultrasonic vibration

This article has been reviewed according to Science X's editorial process and policies. Editors have highlighted the following attributes while ensuring the content's credibility: Researchers at the University of Osaka have developed a catalyst that uses mechanical vibration to convert carbon dioxide (CO2) into carbon monoxide (CO), an important chemical feedstock. The catalyst consists of barium titanate (BaTiO3) coated with a metal-organic framework (MOF)—a porous material that captures and concentrates CO2 near the catalyst surface—and incorporates isolated copper (Cu) atoms as reaction sites.

The design concentrates CO2 near the Cu sites and helps direct the electrical charges generated by vibration to where the reaction occurs. Under ultrasonic vibration, the catalyst produced CO at approximately five times the rate of pristine BaTiO3. The study was published in ACS Catalysis.

Piezocatalysis uses piezoelectric materials that convert mechanical energy, such as vibration, into electrical charges that can drive chemical reactions at room temperature. However, CO2 does not dissolve well in water, limiting the amount that can reach the catalyst surface. Conventional piezocatalysts may also have too few reaction sites and may not use the piezo-induced charges efficiently.

The team developed BaTiO3 nanocubes coated with ZIF-8, a hydrophobic MOF with a high capacity for adsorbing CO2. They then introduced isolated Cu atoms as reaction sites into the coating. The resulting core-shell catalyst, called Cu-ZIF-8/BT, concentrates CO2 near the Cu reaction sites and facilitates the transfer of piezo-induced electrons to these sites.

In water at room temperature and without sacrificial reagents, Cu-ZIF-8/BT produced CO at a rate of 114 μmol g-1 h-1 under ultrasonic vibration. Pristine BaTiO3 produced 24 μmol g-1 h-1 under the same conditions. This result indicates that the new catalyst increased the CO production rate by 4.8 times—approximately fivefold.

Coating BaTiO3 with ZIF-8 without Cu increased the rate to 56 μmol g-1 h-1. In contrast, simply mixing Cu-ZIF-8 and BaTiO3 produced only 16 μmol g-1 h-1. These results show that close contact between the BaTiO3 core and the Cu-ZIF-8 shell is important for improving the catalyst's performance.